|
How do sterilization and
deodorization, which were mentioned in the section on the effects
of ARC-FLASH, occur at the surface of the photocatalytic titanium
dioxide? The explanation here is based on theories that have been
clarified so far; however, basic studies of the precise mechanism
are still under way.
Oxidation-reduction reactions occur repeatedly
on a surface treated with ARC-FLASH. Air is needed for environmental
purification using titanium dioxide. Air always contains oxygen
and water vapor, which are also involved in the reaction mechanism.
| (1) |
Photocatalysis is
initiated when titanium dioxide is exposed to UV rays. This
is called optical solid surface or interface reaction.
Titanium dioxide absorbs UV rays, and electrons and holes are
generated inside it. Electrons and holes near the surface are
involved in reaction. The generation of many electrons and holes
leads to a higher reaction effect. |
 |
|
|
| (2) |
The generated holes
have strong oxidizability, and generate hydroxyl radicals by
reacting with water at the surface of the titanium dioxide. |
 |
|
The generated hydroxyl
radicals have strong oxidizability and cause oxidative reactions
with organic compounds. In the presence of oxygen, radicals
of the intermediates of organic compounds and oxygen molecules
induce a radical chain reaction and consume oxygen. Organic
compounds are then decomposed and eventually turn into carbon
dioxide and water. |
|
|
| (3) |
The generated electrons
generate superoxide anions by causing a reductive reaction with
surface oxygen. |
 |
|
The generated superoxide
anions form oxides by adhering to the intermediates of the oxidation
reaction or turn into hydrogen peroxide and then into water. O is also generated in the air and directly affects
the carbon-carbon bond of organic matter. |
|
|
| (4) |
Organic matter is
a causative agent of germs and odors. Because organic matter
is usually more oxidizable than water, holes are more likely
to be used for oxidation of organic compounds and the recombination
rate of carriers (holes and electrons) decreases when the concentration
of organic matter is higher.Under the condition where all of
the spaces are filled, the transfer of electrons to oxygen molecules
at the reduction site become the rate-determining step of the
entire photocatalytic reaction. In other words, the efficiency
of the reaction is improved by facilitating the transfer of
electrons into oxygen molecules. |
|